Modular Approach to the Synthesis of Unsaturated 1-Monoacyl Glycerols

ABSTRACT A modular synthesis of unsaturated 1-monoacylglycerols (1) from CIS-1-iodo-1-alkenes [CIS-RCH=CHI] and unsaturated carboxylic acids [CH 2 =CH(CH 2 ) n CO 2 H] is described. The method revolves around a Suzuki coupling to establish olefin geometry.

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Bibliographic Details
Published in:Synlett 2004-07, Vol.2004 (8), p.1339-1342
Main Authors: Coleman, Bridgett E., Cwynar, Valerie, Hart, David J., Havas, Fabien, Mohan, Jakkam Madan, Patterson, Suzanne, Ridenour, Sam, Schmidt, Michael, Smith, Eboney, Wells, Angela J.
Format: Article
Language:English
Subjects:
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Summary:ABSTRACT A modular synthesis of unsaturated 1-monoacylglycerols (1) from CIS-1-iodo-1-alkenes [CIS-RCH=CHI] and unsaturated carboxylic acids [CH 2 =CH(CH 2 ) n CO 2 H] is described. The method revolves around a Suzuki coupling to establish olefin geometry.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2004-825616