Iron-Catalyzed Coupling Reaction between 1,1-Dichloro-1-alkenes and Grignard Reagents

Abstract This letter reports the coupling reaction of Grignard ­reagents with 1,1-dichloro-1-alkenes in the presence of the environmentally friendly iron(III) catalyst. This non-toxic procedure is general and provides the di-coupled products as the major compounds. The scope and limitations of this...

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Bibliographic Details
Published in:Synlett 2004-12, Vol.2004 (15), p.2697-2700
Main Authors: Dos Santos, Mickaël, Franck, Xavier, Hocquemiller, Reynald, Figadère, Bruno, Peyrat, Jean-François, Provot, Olivier, Brion, Jean-Daniel, Alami, Mouâd
Format: Article
Language:English
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letter
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Summary:Abstract This letter reports the coupling reaction of Grignard ­reagents with 1,1-dichloro-1-alkenes in the presence of the environmentally friendly iron(III) catalyst. This non-toxic procedure is general and provides the di-coupled products as the major compounds. The scope and limitations of this new reaction are described.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2004-835626