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Zr(Ot-Bu)4-Catalyzed Tishchenko Reduction of β-Hydroxy Ketones

Abstract Zr(OtBu) 4 was found to catalyze the Tishchenko reduction of β-hydroxy ketones giving rise to differentiated 1,3-ANTI-diol monoesters in high yields and excellent stereoselectivity.

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Bibliographic Details
Published in:Synlett 2005-01, Vol.2005 (1), p.91-94
Main Authors: Schneider, Christoph, Klapa, Katharina, Hansch, Markus
Format: Article
Language:English
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Description
Summary:Abstract Zr(OtBu) 4 was found to catalyze the Tishchenko reduction of β-hydroxy ketones giving rise to differentiated 1,3-ANTI-diol monoesters in high yields and excellent stereoselectivity.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2004-836056