Towards Reaction Selectivities of Imines and Aziridines

Abstract Several simple and convenient transformations of imines and aziridines under mild conditions have been developed, rendering access to several kinds of β-amino derivatives, α-amino nitriles and phosphonates, aziridines, and conjugated dienes from imines and aziridines under neutral and metal...

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Bibliographic Details
Published in:Synlett 2006-02, Vol.2006 (2), p.181-193
Main Authors: Hou, Xue Long, Wu, Jie, Fan, Ren Hua, Ding, Chang Hua, Luo, Zhi Bin, Dai, Li Xin
Format: Article
Language:English
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Summary:Abstract Several simple and convenient transformations of imines and aziridines under mild conditions have been developed, rendering access to several kinds of β-amino derivatives, α-amino nitriles and phosphonates, aziridines, and conjugated dienes from imines and aziridines under neutral and metal-free conditions very conveniently. High stereoselectivities are realized in most reactions based upon mechanistic considerations.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2006-926220