Improved Synthesis of Monohalogenated Cavitands and Their Use in the Synthesis of Further Functionalized Cavitands

ABSTRACT A new procedure for the synthesis of monohalogenated cavitands was established, which is at least one step shorter and far more atom-efficient than previously published pathways. These monohalogenated cavitands were demonstrated to be versatile synthons for the synthesis of further function...

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Bibliographic Details
Published in:Synthesis (Stuttgart) 2006-02, Vol.2006 (3), p.519-527
Main Authors: Hass, Oliver, Schierholt, Alexander, Jordan, Markus, Lützen, Arne
Format: Article
Language:English
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Summary:ABSTRACT A new procedure for the synthesis of monohalogenated cavitands was established, which is at least one step shorter and far more atom-efficient than previously published pathways. These monohalogenated cavitands were demonstrated to be versatile synthons for the synthesis of further functionalized derivatives through cyanation, carboxylation, and a series of palladium-catalyzed Suzuki reactions.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2006-926274