A Novel Three-Component Reaction of Triphenylphosphine, DMAD, and Electron-Deficient Styrenes: Facile Synthesis of Cyclopentenyl Phosphoranes

ABSTRACT The zwitterion formed from triphenylphosphine and DMAD adds to electron-deficient styrenes to form stable cyclopentenyl phosphoranes. This is the first example of such a zwitterion in which the phosphine is incorporated into the product

Saved in:
Bibliographic Details
Published in:Synthesis (Stuttgart) 2006-05, Vol.2006 (9), p.1443-1446
Main Authors: Nair, Vijay, Deepthi, Ani, Beneesh, P. B., Eringathodi, Suresh
Format: Article
Language:English
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:ABSTRACT The zwitterion formed from triphenylphosphine and DMAD adds to electron-deficient styrenes to form stable cyclopentenyl phosphoranes. This is the first example of such a zwitterion in which the phosphine is incorporated into the product
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2006-926423