General, Mild and Efficient Synthesis of β-Enaminones Catalyzed by Ceric Ammonium Nitrate

Abstract Ceric ammonium nitrate catalyzes the reaction between aromatic or aliphatic primary amines and a variety of β-dicarbonyl compounds, including β-ketoesters, β-ketothioesters and β-diketones. The reaction proceeds smoothly at room temperature in short reaction times and gives β-enaminones in...

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Bibliographic Details
Published in:Synlett 2007-04, Vol.2007 (6), p.0881-0884
Main Authors: Sridharan, Vellaisamy, Avendaño, Carmen, Menéndez, J. Carlos
Format: Article
Language:English
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Summary:Abstract Ceric ammonium nitrate catalyzes the reaction between aromatic or aliphatic primary amines and a variety of β-dicarbonyl compounds, including β-ketoesters, β-ketothioesters and β-diketones. The reaction proceeds smoothly at room temperature in short reaction times and gives β-enaminones in good to excellent yields.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2007-973862