Raman scattering in a LiNiPO4 single crystal

The complete Raman spectra of a single crystal of LiNiPO4 for a wide temperature range are reported. Of the 36 Raman-active modes predicted by group theory, 33 have been detected. The spectra are successfully analyzed in terms of internal modes of the (PO4)3− group and external modes. Multiphonon Ra...

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Published in:Low temperature physics (Woodbury, N.Y.) N.Y.), 2002-03, Vol.28 (3), p.203-209
Main Authors: Fomin, V. I., Gnezdilov, V. P., Kurnosov, V. S., Peschanskii, A. V., Yeremenko, A. V., Schmid, H., Rivera, J.-P., Gentil, S.
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creator Fomin, V. I.
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description The complete Raman spectra of a single crystal of LiNiPO4 for a wide temperature range are reported. Of the 36 Raman-active modes predicted by group theory, 33 have been detected. The spectra are successfully analyzed in terms of internal modes of the (PO4)3− group and external modes. Multiphonon Raman scattering is also discussed. Low-frequency lines, observed in the antiferromagnetic phase, are assigned to magnon scattering and are discussed briefly.
doi_str_mv 10.1063/1.1468525
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title Raman scattering in a LiNiPO4 single crystal
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