Electron Paramagnetic Resonance and X-Ray Studies in Doped Silver Carbonate

For Y(III)- or Gd(III)-doped silver carbonate with the ratio of dopant to Ag, n ≥ 0.005, a new orthorhombic crystal structure is reported with a = 13.94 Å, b = 5.97 Å, and c = 5.30 Å, determined from x-ray studies. Electron paramagnetic resonance investigations on γ-irradiated Y(III)-doped silver ca...

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Bibliographic Details
Published in:The Journal of chemical physics 1969-07, Vol.51 (2), p.532-538
Main Authors: Ashford, Nicholas A., Snelson, Alan
Format: Article
Language:English
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Summary:For Y(III)- or Gd(III)-doped silver carbonate with the ratio of dopant to Ag, n ≥ 0.005, a new orthorhombic crystal structure is reported with a = 13.94 Å, b = 5.97 Å, and c = 5.30 Å, determined from x-ray studies. Electron paramagnetic resonance investigations on γ-irradiated Y(III)-doped silver carbonate also indicate the presence of a new crystal structure. The same new crystal structure is thermally attained in undoped carbonate at ∼150°C under 3 atm of CO2.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1672030