Ionic Association in Molten AgNO3

An interpretation of the vibrational spectrum of molten silver nitrate based on normal coordinate analysis is presented. The results indicate that ion pairing may be responsible for the observed splitting of one degenerate fundamental and appearance of the infrared-active band in the Raman spectrum....

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Bibliographic Details
Published in:The Journal of chemical physics 1966-01, Vol.44 (2), p.448-450
Main Authors: Wait, S. C., Ward, A. T.
Format: Article
Language:English
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Summary:An interpretation of the vibrational spectrum of molten silver nitrate based on normal coordinate analysis is presented. The results indicate that ion pairing may be responsible for the observed splitting of one degenerate fundamental and appearance of the infrared-active band in the Raman spectrum. A force constant of 0.5 mdyn/Å is estimated for the Ag–O interaction.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1726707