Ionic Association in Molten AgNO3

An interpretation of the vibrational spectrum of molten silver nitrate based on normal coordinate analysis is presented. The results indicate that ion pairing may be responsible for the observed splitting of one degenerate fundamental and appearance of the infrared-active band in the Raman spectrum....

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Published in:The Journal of chemical physics 1966-01, Vol.44 (2), p.448-450
Main Authors: Wait, S. C., Ward, A. T.
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Language:English
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creator Wait, S. C.
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description An interpretation of the vibrational spectrum of molten silver nitrate based on normal coordinate analysis is presented. The results indicate that ion pairing may be responsible for the observed splitting of one degenerate fundamental and appearance of the infrared-active band in the Raman spectrum. A force constant of 0.5 mdyn/Å is estimated for the Ag–O interaction.
doi_str_mv 10.1063/1.1726707
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source AIP_美国物理联合会现刊（与NSTL共建）
title Ionic Association in Molten AgNO3
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