Rates of Reaction of Hydrogen with Iodine

• Published in: The Journal of chemical physics 1959-05, Vol.30 (5), p.1292-1300
• Main Author: Sullivan, John H.
• Format: Article
• Language: English
• ISSN: 0021-9606; 1089-7690
• DOI: 10.1063/1.1730174

The rates of reaction of hydrogen with iodine have been measured at 633.21°, 666.79°, 710.33°, and 737.93°K with at least a tenfold variation in the hydrogen and iodine concentrations at each temperature. The data have been treated considering the elementary reactions to be I2⇌2I(1)H2+I2→2HI(2)HI→H2+I2(3)I+H2→HI+H(4)H+HI→H2+I(5)H+I2→H2+I(6)I+HI→I2+H. This classical reaction has long been considered to consist solely of the simple bimolecular reactions (1) and (2). However, the atom mechanism, reactions (3) to (6), is shown to account for 10% of the over-all reaction at 633° and 27% at 738°K when the iodine pressure is one-half atmosphere. The three independent constants k1, k3, and k4/k5 in (mole/cc)—1 sec—1, are given by log10(k1/T½) = 12.78–40740/4.575T, log10(k3/T½) = 12.75–33440/4.575T, and k4/k5 = 0.07, 0.082, 0.117, 0.125 at the experimental temperatures 633°, 667°, 710°, and 738°K.