On the Theory of Torsional Vibrations of (CH3)3—X Type Molecules

Torsional vibrations of (CH3)3—X type molecules having C3v point group symmetry have been analyzed by using a periodic potential function, and by taking into account mutual top—top interaction terms. The energy scheme was calculated by perturbation methods, and the selection rules have been derived....

Full description

Saved in:
Bibliographic Details
Published in:The Journal of chemical physics 1963-01, Vol.39 (1), p.17-22
Main Authors: Möller, K. D., Andresen, H. G.
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c229t-2d103873541289cfaa08addc67d178ff33d36b6aebdf7a06241b05e28d58f8fc3
cites cdi_FETCH-LOGICAL-c229t-2d103873541289cfaa08addc67d178ff33d36b6aebdf7a06241b05e28d58f8fc3
container_end_page 22
container_issue 1
container_start_page 17
container_title The Journal of chemical physics
container_volume 39
creator Möller, K. D.
Andresen, H. G.
description Torsional vibrations of (CH3)3—X type molecules having C3v point group symmetry have been analyzed by using a periodic potential function, and by taking into account mutual top—top interaction terms. The energy scheme was calculated by perturbation methods, and the selection rules have been derived. For the high-barrier case, two allowed transitions from the ground state to the first excited state can be predicted.
doi_str_mv 10.1063/1.1733997
format article
fullrecord <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1063_1_1733997</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1063_1_1733997</sourcerecordid><originalsourceid>FETCH-LOGICAL-c229t-2d103873541289cfaa08addc67d178ff33d36b6aebdf7a06241b05e28d58f8fc3</originalsourceid><addsrcrecordid>eNotj7tOwzAYRi0EEqEw8AYe6ZDy_3biywgRpUhFXQJiixxf1KDQVHYYsvEQPCFPAhWdzqczfNIh5BphgSD4LS5Qcq61PCEZgtK5FBpOSQbAMNcCxDm5SOkdAFCyIiP3mx0dt57WWz_EiQ6B1kNM3bAzPX3t2mjGv50O_qZa8Tn_-fp-o_W09_R56L397H26JGfB9MlfHTkjL8uHulrl683jU3W3zi1jesyZQ-BK8rJAprQNxoAyzlkhHUoVAueOi1YY37ogDQhWYAulZ8qVKqhg-YzM_39tHFKKPjT72H2YODUIzSG-weYYz38BMS1LTw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>On the Theory of Torsional Vibrations of (CH3)3—X Type Molecules</title><source>AIP - American Institute of Physics</source><creator>Möller, K. D. ; Andresen, H. G.</creator><creatorcontrib>Möller, K. D. ; Andresen, H. G.</creatorcontrib><description>Torsional vibrations of (CH3)3—X type molecules having C3v point group symmetry have been analyzed by using a periodic potential function, and by taking into account mutual top—top interaction terms. The energy scheme was calculated by perturbation methods, and the selection rules have been derived. For the high-barrier case, two allowed transitions from the ground state to the first excited state can be predicted.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.1733997</identifier><language>eng</language><ispartof>The Journal of chemical physics, 1963-01, Vol.39 (1), p.17-22</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c229t-2d103873541289cfaa08addc67d178ff33d36b6aebdf7a06241b05e28d58f8fc3</citedby><cites>FETCH-LOGICAL-c229t-2d103873541289cfaa08addc67d178ff33d36b6aebdf7a06241b05e28d58f8fc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,782,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Möller, K. D.</creatorcontrib><creatorcontrib>Andresen, H. G.</creatorcontrib><title>On the Theory of Torsional Vibrations of (CH3)3—X Type Molecules</title><title>The Journal of chemical physics</title><description>Torsional vibrations of (CH3)3—X type molecules having C3v point group symmetry have been analyzed by using a periodic potential function, and by taking into account mutual top—top interaction terms. The energy scheme was calculated by perturbation methods, and the selection rules have been derived. For the high-barrier case, two allowed transitions from the ground state to the first excited state can be predicted.</description><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1963</creationdate><recordtype>article</recordtype><recordid>eNotj7tOwzAYRi0EEqEw8AYe6ZDy_3biywgRpUhFXQJiixxf1KDQVHYYsvEQPCFPAhWdzqczfNIh5BphgSD4LS5Qcq61PCEZgtK5FBpOSQbAMNcCxDm5SOkdAFCyIiP3mx0dt57WWz_EiQ6B1kNM3bAzPX3t2mjGv50O_qZa8Tn_-fp-o_W09_R56L397H26JGfB9MlfHTkjL8uHulrl683jU3W3zi1jesyZQ-BK8rJAprQNxoAyzlkhHUoVAueOi1YY37ogDQhWYAulZ8qVKqhg-YzM_39tHFKKPjT72H2YODUIzSG-weYYz38BMS1LTw</recordid><startdate>19630101</startdate><enddate>19630101</enddate><creator>Möller, K. D.</creator><creator>Andresen, H. G.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19630101</creationdate><title>On the Theory of Torsional Vibrations of (CH3)3—X Type Molecules</title><author>Möller, K. D. ; Andresen, H. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c229t-2d103873541289cfaa08addc67d178ff33d36b6aebdf7a06241b05e28d58f8fc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1963</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Möller, K. D.</creatorcontrib><creatorcontrib>Andresen, H. G.</creatorcontrib><collection>CrossRef</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Möller, K. D.</au><au>Andresen, H. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>On the Theory of Torsional Vibrations of (CH3)3—X Type Molecules</atitle><jtitle>The Journal of chemical physics</jtitle><date>1963-01-01</date><risdate>1963</risdate><volume>39</volume><issue>1</issue><spage>17</spage><epage>22</epage><pages>17-22</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>Torsional vibrations of (CH3)3—X type molecules having C3v point group symmetry have been analyzed by using a periodic potential function, and by taking into account mutual top—top interaction terms. The energy scheme was calculated by perturbation methods, and the selection rules have been derived. For the high-barrier case, two allowed transitions from the ground state to the first excited state can be predicted.</abstract><doi>10.1063/1.1733997</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0021-9606
ispartof The Journal of chemical physics, 1963-01, Vol.39 (1), p.17-22
issn 0021-9606
1089-7690
language eng
recordid cdi_crossref_primary_10_1063_1_1733997
source AIP - American Institute of Physics
title On the Theory of Torsional Vibrations of (CH3)3—X Type Molecules
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T14%3A28%3A16IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=On%20the%20Theory%20of%20Torsional%20Vibrations%20of%20(CH3)3%E2%80%94X%20Type%20Molecules&rft.jtitle=The%20Journal%20of%20chemical%20physics&rft.au=M%C3%B6ller,%20K.%20D.&rft.date=1963-01-01&rft.volume=39&rft.issue=1&rft.spage=17&rft.epage=22&rft.pages=17-22&rft.issn=0021-9606&rft.eissn=1089-7690&rft_id=info:doi/10.1063/1.1733997&rft_dat=%3Ccrossref%3E10_1063_1_1733997%3C/crossref%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c229t-2d103873541289cfaa08addc67d178ff33d36b6aebdf7a06241b05e28d58f8fc3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true