Solvent Action on Optical Rotatory Power. II. The Quadrupole Field of the CS2 Type Molecule

The applications of the general expression for the vectorial solvent field in organic liquids are further extended by detailed consideration of quadrupole molecules of the types CS2. The results of the computation are found satisfying from a theoretical standpoint. The experimental control is undert...

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Bibliographic Details
Published in:The Journal of chemical physics 1938-03, Vol.6 (3), p.163-167
Main Authors: Cohen, Karl, Beckmann, Charles O.
Format: Article
Language:English
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Summary:The applications of the general expression for the vectorial solvent field in organic liquids are further extended by detailed consideration of quadrupole molecules of the types CS2. The results of the computation are found satisfying from a theoretical standpoint. The experimental control is undertaken with the aid of a previously developed theory of optical rotatory power in solution. The results are found to be in accord with the existing data.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1750217