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Lithium iodate nanocrystals in Laponite matrixfor nonlinear optical applications

A Laponite clay-based lithium iodate nanocomposite have been synthesized for nonlinear optical applications. After addition of lithium iodate aqueous solution to a colloidal suspension of Laponite JS, thin layers are elaborated from this sol using dip-coating technique. After drying and heat treatme...

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Bibliographic Details
Published in:Applied physics letters 2004-08, Vol.85 (5), p.710-711
Main Authors: Teyssier, Jérémie, Dantec, Ronan Le, Galez, Christine, Mugnier, Yannick, Bouillot, Jacques, Plenet, Jean-Claude
Format: Article
Language:eng ; jpn
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Summary:A Laponite clay-based lithium iodate nanocomposite have been synthesized for nonlinear optical applications. After addition of lithium iodate aqueous solution to a colloidal suspension of Laponite JS, thin layers are elaborated from this sol using dip-coating technique. After drying and heat treatments between 150 and 220°C, LiIO3 crystallizes in the matrix with nanometer size. As a result of their strong dipolar moment, the LiIO3 crystals can be orientated under an external electric field during nucleation. Planar waveguides have been elaborated on glass substrates and studied using m-lines spectroscopy. The experimental nonlinear optical response has been compared to predictions of a model and an effective nonlinear coefficient deff=1.4pm∕V has been measured.
ISSN:0003-6951
1077-3118
DOI:10.1063/1.1777411