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Excitation photocapacitance study of EL2 in n - GaAs prepared by annealing under different arsenic vapor pressures

The excitation photocapacitance method was applied to n - GaAs : Te ( n = 4 × 10 16 cm − 3 ) prepared by annealing under various excess arsenic vapor pressures. By changing the primary excitation photon energies, the emission spectra for the EL 2 0 → EL 2 + and EL 2 + → EL 2 + + transitions were det...

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Bibliographic Details
Published in:Journal of applied physics 2005-02, Vol.97 (3), p.033705-033705-6
Main Authors: Oyama, Yutaka, Nishizawa, Jun-ichi
Format: Article
Language:English
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Summary:The excitation photocapacitance method was applied to n - GaAs : Te ( n = 4 × 10 16 cm − 3 ) prepared by annealing under various excess arsenic vapor pressures. By changing the primary excitation photon energies, the emission spectra for the EL 2 0 → EL 2 + and EL 2 + → EL 2 + + transitions were determined. Considering the electron capture processes of the valence band ( VB ) → EL 2 + ( 0.67 eV ) and VB → EL 2 + + ( 0.47 eV ) at 77 K , the Frank-Condon shifts ( d FC ) of the annealed GaAs crystals were determined for the EL 2 + level on the basis of the configuration coordinate model. It was shown that the lattice relaxation around the EL 2 level is larger under arsenic-poor conditions, and thus it is considered that arsenic vacancies are closely related with the atomic configuration of the EL 2 defect, in combination with excess arsenic defects.
ISSN:0021-8979
1089-7550
DOI:10.1063/1.1839635