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Solution-processed n-type organic thin-film transistors with high field-effect mobility

We report the performance of solution-processed n-type organic thin-film transistors (OTFTs) based on C60 derivatives. Long-chain alkyl-substituted C60, C60-fused N-methylpyrrolidine-meta-C12 phenyl (C60MC12), was used as a semiconducting layer. The C60MC12-thin-film transistor shows high electron m...

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Bibliographic Details
Published in:Applied physics letters 2005-11, Vol.87 (20)
Main Authors: Chikamatsu, Masayuki, Nagamatsu, Shuichi, Yoshida, Yuji, Saito, Kazuhiro, Yase, Kiyoshi, Kikuchi, Koichi
Format: Article
Language:English
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Summary:We report the performance of solution-processed n-type organic thin-film transistors (OTFTs) based on C60 derivatives. Long-chain alkyl-substituted C60, C60-fused N-methylpyrrolidine-meta-C12 phenyl (C60MC12), was used as a semiconducting layer. The C60MC12-thin-film transistor shows high electron mobility of 0.067cm2∕Vs in saturation regime. From the result of x-ray diffraction analysis, the C60MC12 active layer forms highly ordered crystalline film. We found that self-assemble ability of long alkyl chains plays an important role for fabrication of highly ordered crystalline film, leading to achievement of high electron mobility in solution-processed n-type OTFTs.
ISSN:0003-6951
1077-3118
DOI:10.1063/1.2130712