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High conductivity of Ga-doped rock-salt ZnO under pressure:Hint on deep-ultraviolet-transparent conducting oxides
This letter reports on transport and optical experiments under pressure in thin films of Ga-doped ZnO in both the wurtzite and rock-salt phases. The conductivity of heavily Ga-doped ZnO thin films is shown to decrease by only a factor of 2 in the wurtzite-to-rock-salt phase transition, occurring at...
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Published in: | Applied physics letters 2006-01, Vol.88 (1), p.011910-011910-3 |
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container_title | Applied physics letters |
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creator | Segura, A. Sans, J. A. Errandonea, D. Martinez-García, D. Fages, V. |
description | This letter reports on transport and optical experiments under pressure in thin films of Ga-doped ZnO in both the wurtzite and rock-salt phases. The conductivity of heavily Ga-doped ZnO thin films is shown to decrease by only a factor of 2 in the wurtzite-to-rock-salt phase transition, occurring at about 11.5 GPa, while the optical gap increases from 4 to more than 5 eV. Ga-doped rock-salt ZnO is shown to behave as a deep-ultraviolet-transparent conducting oxide, with resistivity values as low as
10
−
3
Ω
cm
. The analysis of Burstein-Moss shift and free carrier absorption in rock-salt ZnO yield an estimation of the electron-hole reduced effective mass and electronic dielectric constant. Given the similarity between the electronic structures of rock-salt ZnO under pressure and rock-salt
Mg
x
Zn
1
−
x
O
at ambient pressure, this alloy could be a good deep-ultraviolet-transparent conducting oxide. |
doi_str_mv | 10.1063/1.2161392 |
format | article |
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10
−
3
Ω
cm
. The analysis of Burstein-Moss shift and free carrier absorption in rock-salt ZnO yield an estimation of the electron-hole reduced effective mass and electronic dielectric constant. Given the similarity between the electronic structures of rock-salt ZnO under pressure and rock-salt
Mg
x
Zn
1
−
x
O
at ambient pressure, this alloy could be a good deep-ultraviolet-transparent conducting oxide.</description><identifier>ISSN: 0003-6951</identifier><identifier>EISSN: 1077-3118</identifier><identifier>DOI: 10.1063/1.2161392</identifier><identifier>CODEN: APPLAB</identifier><language>eng</language><publisher>American Institute of Physics</publisher><ispartof>Applied physics letters, 2006-01, Vol.88 (1), p.011910-011910-3</ispartof><rights>2006 American Institute of Physics</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c350t-bc3ebb8493302f8ab4058630a8ff4798603b78d8e344999b2cce440983cd8f813</citedby><cites>FETCH-LOGICAL-c350t-bc3ebb8493302f8ab4058630a8ff4798603b78d8e344999b2cce440983cd8f813</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/apl/article-lookup/doi/10.1063/1.2161392$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>314,780,782,784,795,27924,27925,76383</link.rule.ids></links><search><creatorcontrib>Segura, A.</creatorcontrib><creatorcontrib>Sans, J. A.</creatorcontrib><creatorcontrib>Errandonea, D.</creatorcontrib><creatorcontrib>Martinez-García, D.</creatorcontrib><creatorcontrib>Fages, V.</creatorcontrib><title>High conductivity of Ga-doped rock-salt ZnO under pressure:Hint on deep-ultraviolet-transparent conducting oxides</title><title>Applied physics letters</title><description>This letter reports on transport and optical experiments under pressure in thin films of Ga-doped ZnO in both the wurtzite and rock-salt phases. The conductivity of heavily Ga-doped ZnO thin films is shown to decrease by only a factor of 2 in the wurtzite-to-rock-salt phase transition, occurring at about 11.5 GPa, while the optical gap increases from 4 to more than 5 eV. Ga-doped rock-salt ZnO is shown to behave as a deep-ultraviolet-transparent conducting oxide, with resistivity values as low as
10
−
3
Ω
cm
. The analysis of Burstein-Moss shift and free carrier absorption in rock-salt ZnO yield an estimation of the electron-hole reduced effective mass and electronic dielectric constant. Given the similarity between the electronic structures of rock-salt ZnO under pressure and rock-salt
Mg
x
Zn
1
−
x
O
at ambient pressure, this alloy could be a good deep-ultraviolet-transparent conducting oxide.</description><issn>0003-6951</issn><issn>1077-3118</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNp1kDtPwzAUhS0EEqUw8A-8MrjYuXk4DEioghapUhdYWCLHj2IIdrCdiv57glokFqZzj-6nM3wIXTI6Y7SEazbLWMmgzo7QhNGqIsAYP0YTSimQsi7YKTqL8W2sRQYwQZ9Lu3nF0js1yGS3Nu2wN3ghiPK9Vjh4-U6i6BJ-cWs8OKUD7oOOcQj6Zmldwt5hpXVPhi4FsbW-04mMl4u9CHr8_067DfZfVul4jk6M6KK-OOQUPT_cP82XZLVePM7vVkRCQRNpJei25XkNQDPDRZvTgpdABTcmr2peUmgrrriGPK_rus2k1HlOaw5SccMZTNHVflcGH2PQpumD_RBh1zDa_LhqWHNwNbK3ezZKm0Sy3v0P_whr_gprvIFvZ-BzAQ</recordid><startdate>20060102</startdate><enddate>20060102</enddate><creator>Segura, A.</creator><creator>Sans, J. A.</creator><creator>Errandonea, D.</creator><creator>Martinez-García, D.</creator><creator>Fages, V.</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20060102</creationdate><title>High conductivity of Ga-doped rock-salt ZnO under pressure:Hint on deep-ultraviolet-transparent conducting oxides</title><author>Segura, A. ; Sans, J. A. ; Errandonea, D. ; Martinez-García, D. ; Fages, V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c350t-bc3ebb8493302f8ab4058630a8ff4798603b78d8e344999b2cce440983cd8f813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Segura, A.</creatorcontrib><creatorcontrib>Sans, J. A.</creatorcontrib><creatorcontrib>Errandonea, D.</creatorcontrib><creatorcontrib>Martinez-García, D.</creatorcontrib><creatorcontrib>Fages, V.</creatorcontrib><collection>CrossRef</collection><jtitle>Applied physics letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Segura, A.</au><au>Sans, J. A.</au><au>Errandonea, D.</au><au>Martinez-García, D.</au><au>Fages, V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High conductivity of Ga-doped rock-salt ZnO under pressure:Hint on deep-ultraviolet-transparent conducting oxides</atitle><jtitle>Applied physics letters</jtitle><date>2006-01-02</date><risdate>2006</risdate><volume>88</volume><issue>1</issue><spage>011910</spage><epage>011910-3</epage><pages>011910-011910-3</pages><issn>0003-6951</issn><eissn>1077-3118</eissn><coden>APPLAB</coden><abstract>This letter reports on transport and optical experiments under pressure in thin films of Ga-doped ZnO in both the wurtzite and rock-salt phases. The conductivity of heavily Ga-doped ZnO thin films is shown to decrease by only a factor of 2 in the wurtzite-to-rock-salt phase transition, occurring at about 11.5 GPa, while the optical gap increases from 4 to more than 5 eV. Ga-doped rock-salt ZnO is shown to behave as a deep-ultraviolet-transparent conducting oxide, with resistivity values as low as
10
−
3
Ω
cm
. The analysis of Burstein-Moss shift and free carrier absorption in rock-salt ZnO yield an estimation of the electron-hole reduced effective mass and electronic dielectric constant. Given the similarity between the electronic structures of rock-salt ZnO under pressure and rock-salt
Mg
x
Zn
1
−
x
O
at ambient pressure, this alloy could be a good deep-ultraviolet-transparent conducting oxide.</abstract><pub>American Institute of Physics</pub><doi>10.1063/1.2161392</doi></addata></record> |
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title | High conductivity of Ga-doped rock-salt ZnO under pressure:Hint on deep-ultraviolet-transparent conducting oxides |
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