Loading…

The rotational spectrum of the NiI radical in the XΔ5∕22 and AΠ3∕22 states

The millimeter- and submillimeter-wave spectra of the NiI radical in the XΔ5∕22 and AΠ3∕22 states were observed by a source-modulated microwave spectrometer. The NiI radical was generated by a dc glow discharge in the mixture of CH3I vapor and Ar gas through the sputtering reaction with a Ni cathode...

Full description

Saved in:
Bibliographic Details
Published in:The Journal of chemical physics 2006-06, Vol.124 (22)
Main Authors: Miyazawa, Toru, Okabayashi, Emi Y., Koto, Fumi, Tanimoto, Mitsutoshi, Okabayashi, Toshiaki
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c1758-d62951dd00a3382f57a18c3831fceca85d1166187dfd549b971e65481b28b7f13
cites cdi_FETCH-LOGICAL-c1758-d62951dd00a3382f57a18c3831fceca85d1166187dfd549b971e65481b28b7f13
container_end_page
container_issue 22
container_start_page
container_title The Journal of chemical physics
container_volume 124
creator Miyazawa, Toru
Okabayashi, Emi Y.
Koto, Fumi
Tanimoto, Mitsutoshi
Okabayashi, Toshiaki
description The millimeter- and submillimeter-wave spectra of the NiI radical in the XΔ5∕22 and AΠ3∕22 states were observed by a source-modulated microwave spectrometer. The NiI radical was generated by a dc glow discharge in the mixture of CH3I vapor and Ar gas through the sputtering reaction with a Ni cathode. Observed transition frequencies for each electronic state were independently analyzed using a polynomial energy expression based on Hund’s case (c) approximation. The deperturbed rotational constants were also estimated by the perturbation analysis including interaction terms between the ground state and the lowest excited state.
doi_str_mv 10.1063/1.2204918
format article
fullrecord <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1063_1_2204918</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1063_1_2204918</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1758-d62951dd00a3382f57a18c3831fceca85d1166187dfd549b971e65481b28b7f13</originalsourceid><addsrcrecordid>eNotkDtOAzEURS0EEiFQsAO3FBPes8e_MoqARIqAIkh0I48_YlAyE9lDwQ5YAPSsKItgJQwk1dW9RzrFJeQSYYIg-TVOGIPSoD4iIwRtCiUNHJMRAMPCSJCn5CznVwBAxcoReVy9BJq63vZN19o1zdvg-vS2oV2k_YDumwVN1jduYE37Pz3vPsXPxxdj1LaeTnfffN_yIAn5nJxEu87h4pBj8nR7s5rNi-XD3WI2XRYOldCFl8wI9B7Acq5ZFMqidlxzjC44q4VHlBK18tGL0tRGYZCi1FgzXauIfEyu9l6XupxTiNU2NRub3iuE6u-KCqvDFfwX92dQ1A</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>The rotational spectrum of the NiI radical in the XΔ5∕22 and AΠ3∕22 states</title><source>American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list)</source><source>American Institute of Physics</source><creator>Miyazawa, Toru ; Okabayashi, Emi Y. ; Koto, Fumi ; Tanimoto, Mitsutoshi ; Okabayashi, Toshiaki</creator><creatorcontrib>Miyazawa, Toru ; Okabayashi, Emi Y. ; Koto, Fumi ; Tanimoto, Mitsutoshi ; Okabayashi, Toshiaki</creatorcontrib><description>The millimeter- and submillimeter-wave spectra of the NiI radical in the XΔ5∕22 and AΠ3∕22 states were observed by a source-modulated microwave spectrometer. The NiI radical was generated by a dc glow discharge in the mixture of CH3I vapor and Ar gas through the sputtering reaction with a Ni cathode. Observed transition frequencies for each electronic state were independently analyzed using a polynomial energy expression based on Hund’s case (c) approximation. The deperturbed rotational constants were also estimated by the perturbation analysis including interaction terms between the ground state and the lowest excited state.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.2204918</identifier><language>eng</language><ispartof>The Journal of chemical physics, 2006-06, Vol.124 (22)</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1758-d62951dd00a3382f57a18c3831fceca85d1166187dfd549b971e65481b28b7f13</citedby><cites>FETCH-LOGICAL-c1758-d62951dd00a3382f57a18c3831fceca85d1166187dfd549b971e65481b28b7f13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,782,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Miyazawa, Toru</creatorcontrib><creatorcontrib>Okabayashi, Emi Y.</creatorcontrib><creatorcontrib>Koto, Fumi</creatorcontrib><creatorcontrib>Tanimoto, Mitsutoshi</creatorcontrib><creatorcontrib>Okabayashi, Toshiaki</creatorcontrib><title>The rotational spectrum of the NiI radical in the XΔ5∕22 and AΠ3∕22 states</title><title>The Journal of chemical physics</title><description>The millimeter- and submillimeter-wave spectra of the NiI radical in the XΔ5∕22 and AΠ3∕22 states were observed by a source-modulated microwave spectrometer. The NiI radical was generated by a dc glow discharge in the mixture of CH3I vapor and Ar gas through the sputtering reaction with a Ni cathode. Observed transition frequencies for each electronic state were independently analyzed using a polynomial energy expression based on Hund’s case (c) approximation. The deperturbed rotational constants were also estimated by the perturbation analysis including interaction terms between the ground state and the lowest excited state.</description><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNotkDtOAzEURS0EEiFQsAO3FBPes8e_MoqARIqAIkh0I48_YlAyE9lDwQ5YAPSsKItgJQwk1dW9RzrFJeQSYYIg-TVOGIPSoD4iIwRtCiUNHJMRAMPCSJCn5CznVwBAxcoReVy9BJq63vZN19o1zdvg-vS2oV2k_YDumwVN1jduYE37Pz3vPsXPxxdj1LaeTnfffN_yIAn5nJxEu87h4pBj8nR7s5rNi-XD3WI2XRYOldCFl8wI9B7Acq5ZFMqidlxzjC44q4VHlBK18tGL0tRGYZCi1FgzXauIfEyu9l6XupxTiNU2NRub3iuE6u-KCqvDFfwX92dQ1A</recordid><startdate>20060614</startdate><enddate>20060614</enddate><creator>Miyazawa, Toru</creator><creator>Okabayashi, Emi Y.</creator><creator>Koto, Fumi</creator><creator>Tanimoto, Mitsutoshi</creator><creator>Okabayashi, Toshiaki</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20060614</creationdate><title>The rotational spectrum of the NiI radical in the XΔ5∕22 and AΠ3∕22 states</title><author>Miyazawa, Toru ; Okabayashi, Emi Y. ; Koto, Fumi ; Tanimoto, Mitsutoshi ; Okabayashi, Toshiaki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1758-d62951dd00a3382f57a18c3831fceca85d1166187dfd549b971e65481b28b7f13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Miyazawa, Toru</creatorcontrib><creatorcontrib>Okabayashi, Emi Y.</creatorcontrib><creatorcontrib>Koto, Fumi</creatorcontrib><creatorcontrib>Tanimoto, Mitsutoshi</creatorcontrib><creatorcontrib>Okabayashi, Toshiaki</creatorcontrib><collection>CrossRef</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Miyazawa, Toru</au><au>Okabayashi, Emi Y.</au><au>Koto, Fumi</au><au>Tanimoto, Mitsutoshi</au><au>Okabayashi, Toshiaki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The rotational spectrum of the NiI radical in the XΔ5∕22 and AΠ3∕22 states</atitle><jtitle>The Journal of chemical physics</jtitle><date>2006-06-14</date><risdate>2006</risdate><volume>124</volume><issue>22</issue><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>The millimeter- and submillimeter-wave spectra of the NiI radical in the XΔ5∕22 and AΠ3∕22 states were observed by a source-modulated microwave spectrometer. The NiI radical was generated by a dc glow discharge in the mixture of CH3I vapor and Ar gas through the sputtering reaction with a Ni cathode. Observed transition frequencies for each electronic state were independently analyzed using a polynomial energy expression based on Hund’s case (c) approximation. The deperturbed rotational constants were also estimated by the perturbation analysis including interaction terms between the ground state and the lowest excited state.</abstract><doi>10.1063/1.2204918</doi><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0021-9606
ispartof The Journal of chemical physics, 2006-06, Vol.124 (22)
issn 0021-9606
1089-7690
language eng
recordid cdi_crossref_primary_10_1063_1_2204918
source American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list); American Institute of Physics
title The rotational spectrum of the NiI radical in the XΔ5∕22 and AΠ3∕22 states
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-23T23%3A09%3A46IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20rotational%20spectrum%20of%20the%20NiI%20radical%20in%20the%20X%CE%945%E2%88%9522%20and%20A%CE%A03%E2%88%9522%20states&rft.jtitle=The%20Journal%20of%20chemical%20physics&rft.au=Miyazawa,%20Toru&rft.date=2006-06-14&rft.volume=124&rft.issue=22&rft.issn=0021-9606&rft.eissn=1089-7690&rft_id=info:doi/10.1063/1.2204918&rft_dat=%3Ccrossref%3E10_1063_1_2204918%3C/crossref%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c1758-d62951dd00a3382f57a18c3831fceca85d1166187dfd549b971e65481b28b7f13%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true