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Broadband energy-harvesting hybrid solar cells employing nanocomposites of polythiophene:ternary PbSSe nanocrystals

Hybrid solar cells (HSCs) incorporating narrow band gap PbSSe nanocrystals (NCs) in a conjugated polymer were developed for the extensive use of solar radiation up to the near infrared (NIR) range. The developed cell, composed of poly(3-hexylthiophene) (P3HT):PbSSe NC composites with 1:1 weight rati...

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Bibliographic Details
Published in:Applied physics letters 2011-12, Vol.99 (23), p.233115-233115-3
Main Authors: Nam, Minwoo, Kim, Sungwoo, Kim, Taehoon, Kim, Sang-Wook, Lee, Kee-Keun
Format: Article
Language:English
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Summary:Hybrid solar cells (HSCs) incorporating narrow band gap PbSSe nanocrystals (NCs) in a conjugated polymer were developed for the extensive use of solar radiation up to the near infrared (NIR) range. The developed cell, composed of poly(3-hexylthiophene) (P3HT):PbSSe NC composites with 1:1 weight ratio, exhibited a large light-harvesting efficiency over a broad range, in which the external quantum efficiency reached 0.3% at 1100nm. These promising results were attributed to the well-assembled percolation networks with large interfacial junctions and the efficient use of broad solar spectrum due to the use of narrow band gap ternary NCs.
ISSN:0003-6951
1077-3118
DOI:10.1063/1.3669515