The J = 1 para levels of the v = 0 to 6 n p singlet Rydberg series of molecular hydrogen revisited

The energies and the widths of the J = 1 para levels of the v = 0 to 6 Rydberg n p singlet series of molecular hydrogen with absolute intensities of the R(0) and P(2) absorption lines were measured by a high - resolution synchrotron radiation experiment and calculated through a full ab initio multic...

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Bibliographic Details
Published in:The Journal of chemical physics 2012-04, Vol.136 (13), p.134301-134301-12
Main Authors: Glass-Maujean, M., Schmoranzer, H., Haar, I., Knie, A., Reiss, P., Ehresmann, A.
Format: Article
Language:English
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Summary:The energies and the widths of the J = 1 para levels of the v = 0 to 6 Rydberg n p singlet series of molecular hydrogen with absolute intensities of the R(0) and P(2) absorption lines were measured by a high - resolution synchrotron radiation experiment and calculated through a full ab initio multichannel quantum defect theory approach. On the basis of the agreement between theory and experiment, 31 levels were either reassigned or assigned for the first time.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.3697967