Coulombic reactions of polyelectrolytes with counterions of different sizes

Implicit equations were derived for interactions between a charged rod polyelectrolyte model and counterions of different size. The selectivity of the polymer for the smaller of two counterions as a function of its charge density, distances of approach and annular volume was calculated. Ion binding...

Full description

Saved in:
Bibliographic Details
Published in:The Journal of chemical physics 1977-03, Vol.66 (5), p.1934-1939
Main Authors: Gregor, Harry P., Gregor, John M.
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c227t-6abb180b43657c9e5f55d85d3fa401f08e77a69d1c7f5a4afc3469b806fb8f103
cites cdi_FETCH-LOGICAL-c227t-6abb180b43657c9e5f55d85d3fa401f08e77a69d1c7f5a4afc3469b806fb8f103
container_end_page 1939
container_issue 5
container_start_page 1934
container_title The Journal of chemical physics
container_volume 66
creator Gregor, Harry P.
Gregor, John M.
description Implicit equations were derived for interactions between a charged rod polyelectrolyte model and counterions of different size. The selectivity of the polymer for the smaller of two counterions as a function of its charge density, distances of approach and annular volume was calculated. Ion binding (site binding) was calculated by assigning a finite thickness to the Stern layer so as to include a finite number of closely held counterions. Further refinements included the consideration of counterion polarizability as a function of the electric field.
doi_str_mv 10.1063/1.434192
format article
fullrecord <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1063_1_434192</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1063_1_434192</sourcerecordid><originalsourceid>FETCH-LOGICAL-c227t-6abb180b43657c9e5f55d85d3fa401f08e77a69d1c7f5a4afc3469b806fb8f103</originalsourceid><addsrcrecordid>eNo1kM1KAzEURoMoOFbBR8jSzdR7J3-TpQxqxYIbXQ9JJsHItClJitSnV6muzrc4fItDyDXCEkGyW1xyxlF3J6RB6HWrpIZT0gB02GoJ8pxclPIBAKg63pDnIe3ntLHR0eyNqzFtC02B7tJ88LN3Nf-M6gv9jPWdurTfVp__pSmG4LPfVlrily-X5CyYufirPy7I28P967Bq1y-PT8PdunVdp2orjbXYg-VMCuW0F0GIqRcTC4YDBui9UkbqCZ0KwnATHONS2x5ksH1AYAtyc_x1OZWSfRh3OW5MPowI42-EEcdjBPYNVBZQAQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Coulombic reactions of polyelectrolytes with counterions of different sizes</title><source>American Institute of Physics (AIP) Publications</source><creator>Gregor, Harry P. ; Gregor, John M.</creator><creatorcontrib>Gregor, Harry P. ; Gregor, John M.</creatorcontrib><description>Implicit equations were derived for interactions between a charged rod polyelectrolyte model and counterions of different size. The selectivity of the polymer for the smaller of two counterions as a function of its charge density, distances of approach and annular volume was calculated. Ion binding (site binding) was calculated by assigning a finite thickness to the Stern layer so as to include a finite number of closely held counterions. Further refinements included the consideration of counterion polarizability as a function of the electric field.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.434192</identifier><language>eng</language><ispartof>The Journal of chemical physics, 1977-03, Vol.66 (5), p.1934-1939</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c227t-6abb180b43657c9e5f55d85d3fa401f08e77a69d1c7f5a4afc3469b806fb8f103</citedby><cites>FETCH-LOGICAL-c227t-6abb180b43657c9e5f55d85d3fa401f08e77a69d1c7f5a4afc3469b806fb8f103</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,782,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Gregor, Harry P.</creatorcontrib><creatorcontrib>Gregor, John M.</creatorcontrib><title>Coulombic reactions of polyelectrolytes with counterions of different sizes</title><title>The Journal of chemical physics</title><description>Implicit equations were derived for interactions between a charged rod polyelectrolyte model and counterions of different size. The selectivity of the polymer for the smaller of two counterions as a function of its charge density, distances of approach and annular volume was calculated. Ion binding (site binding) was calculated by assigning a finite thickness to the Stern layer so as to include a finite number of closely held counterions. Further refinements included the consideration of counterion polarizability as a function of the electric field.</description><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1977</creationdate><recordtype>article</recordtype><recordid>eNo1kM1KAzEURoMoOFbBR8jSzdR7J3-TpQxqxYIbXQ9JJsHItClJitSnV6muzrc4fItDyDXCEkGyW1xyxlF3J6RB6HWrpIZT0gB02GoJ8pxclPIBAKg63pDnIe3ntLHR0eyNqzFtC02B7tJ88LN3Nf-M6gv9jPWdurTfVp__pSmG4LPfVlrily-X5CyYufirPy7I28P967Bq1y-PT8PdunVdp2orjbXYg-VMCuW0F0GIqRcTC4YDBui9UkbqCZ0KwnATHONS2x5ksH1AYAtyc_x1OZWSfRh3OW5MPowI42-EEcdjBPYNVBZQAQ</recordid><startdate>19770301</startdate><enddate>19770301</enddate><creator>Gregor, Harry P.</creator><creator>Gregor, John M.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19770301</creationdate><title>Coulombic reactions of polyelectrolytes with counterions of different sizes</title><author>Gregor, Harry P. ; Gregor, John M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c227t-6abb180b43657c9e5f55d85d3fa401f08e77a69d1c7f5a4afc3469b806fb8f103</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1977</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gregor, Harry P.</creatorcontrib><creatorcontrib>Gregor, John M.</creatorcontrib><collection>CrossRef</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gregor, Harry P.</au><au>Gregor, John M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Coulombic reactions of polyelectrolytes with counterions of different sizes</atitle><jtitle>The Journal of chemical physics</jtitle><date>1977-03-01</date><risdate>1977</risdate><volume>66</volume><issue>5</issue><spage>1934</spage><epage>1939</epage><pages>1934-1939</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>Implicit equations were derived for interactions between a charged rod polyelectrolyte model and counterions of different size. The selectivity of the polymer for the smaller of two counterions as a function of its charge density, distances of approach and annular volume was calculated. Ion binding (site binding) was calculated by assigning a finite thickness to the Stern layer so as to include a finite number of closely held counterions. Further refinements included the consideration of counterion polarizability as a function of the electric field.</abstract><doi>10.1063/1.434192</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0021-9606
ispartof The Journal of chemical physics, 1977-03, Vol.66 (5), p.1934-1939
issn 0021-9606
1089-7690
language eng
recordid cdi_crossref_primary_10_1063_1_434192
source American Institute of Physics (AIP) Publications
title Coulombic reactions of polyelectrolytes with counterions of different sizes
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T17%3A05%3A09IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Coulombic%20reactions%20of%20polyelectrolytes%20with%20counterions%20of%20different%20sizes&rft.jtitle=The%20Journal%20of%20chemical%20physics&rft.au=Gregor,%20Harry%20P.&rft.date=1977-03-01&rft.volume=66&rft.issue=5&rft.spage=1934&rft.epage=1939&rft.pages=1934-1939&rft.issn=0021-9606&rft.eissn=1089-7690&rft_id=info:doi/10.1063/1.434192&rft_dat=%3Ccrossref%3E10_1063_1_434192%3C/crossref%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c227t-6abb180b43657c9e5f55d85d3fa401f08e77a69d1c7f5a4afc3469b806fb8f103%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true