Structure of the HNCH2CO2− radical trapped in α glycine single crystals

Single crystals of α glycine were γ irradiated and then photolyzed at 77 K. The structure of the HNCH2 CO2− radical so formed and its position in the crystal have been determined by single crystal ESR measurements. The factors controlling the reactivity of this radical in the matrix at 173 K are sug...

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Bibliographic Details
Published in:The Journal of chemical physics 1977-12, Vol.67 (12), p.5658-5660
Main Authors: Iacona, C., Michaut, J. P., Roncin, J.
Format: Article
Language:English
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Summary:Single crystals of α glycine were γ irradiated and then photolyzed at 77 K. The structure of the HNCH2 CO2− radical so formed and its position in the crystal have been determined by single crystal ESR measurements. The factors controlling the reactivity of this radical in the matrix at 173 K are suggested.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.434819