Two-photon excitation spectroscopy of a substituted all- trans hexatriene (iso-tachysterol). Spectroscopic assignments of the low-lying 1‘‘1 B u +’’ and 2‘‘1 A g −’’ ππ states

The two-photon excitation spectrum of the substituted all-trans hexatriene, iso-tachysterol, is taken in EPA (77 K). Comparison of this spectrum with the one-photon absorption and fluorescence spectra indicate that the system origin of the 2’’ 1A*−’’g state lies slightly below the 1’’ 1B*+’’u system...

Full description

Saved in:
Bibliographic Details
Published in:The Journal of chemical physics 1982-12, Vol.77 (12), p.6343-6344
Main Authors: Pierce, Brian M., Bennett, James A., Birge, Robert R.
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The two-photon excitation spectrum of the substituted all-trans hexatriene, iso-tachysterol, is taken in EPA (77 K). Comparison of this spectrum with the one-photon absorption and fluorescence spectra indicate that the system origin of the 2’’ 1A*−’’g state lies slightly below the 1’’ 1B*+’’u system origin in EPA (77 K). (AIP)
ISSN:0021-9606
1089-7690
DOI:10.1063/1.443808