Divalent rhodium hexacyanide in KCl host lattice: An ESR study

The [Rg(CN)6]4− paramagnetic species is unambiguously identified by electron spin resonance spectroscopy. This species is produced when KCl single crystals doped with small amounts of K3Rh(CN)6 are submitted to 2 MeV electron irradiation at 77 K. The existence of an asymmetrical localized phonon mod...

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Bibliographic Details
Published in:The Journal of chemical physics 1983-02, Vol.78 (4), p.2099-2100
Main Authors: Vugman, N. V., Franco, W. O.
Format: Article
Language:English
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Summary:The [Rg(CN)6]4− paramagnetic species is unambiguously identified by electron spin resonance spectroscopy. This species is produced when KCl single crystals doped with small amounts of K3Rh(CN)6 are submitted to 2 MeV electron irradiation at 77 K. The existence of an asymmetrical localized phonon mode is postulated in order to explain the temperature dependence of the measured spin Hamiltonian parameters.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.444923