Surfactant interactions in oil continuous microemulsions

We have used light scattering to determine the interaction potential between the surfactant coated water droplets in an oil continuous microemulsion system. The forward extrapolated zero angle scattering intensities at various water volume fractions were analyzed in terms of the Carnahan–Starling ha...

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Bibliographic Details
Published in:The Journal of chemical physics 1985, Vol.82 (1), p.480-484
Main Author: HUANG, J. S
Format: Article
Language:English
Subjects:
Chemistry
Colloidal state and disperse state
Exact sciences and technology
General and physical chemistry
Physical and chemical studies. Granulometry. Electrokinetic phenomena
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Summary:We have used light scattering to determine the interaction potential between the surfactant coated water droplets in an oil continuous microemulsion system. The forward extrapolated zero angle scattering intensities at various water volume fractions were analyzed in terms of the Carnahan–Starling hard-sphere model modified for two-body attractive interactions. It was found that interparticle attractive interaction due to the overlapping of the surfactant tails could explain the observed phase behavior with respect to changes in the carbon chain length of the oil phase, as well as the existence of the lower critical point. It is further found that the optically determined potential is consistent with the microscopic results obtained with small angle neutron scattering experiments.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.448770