The n = 2,3 triplet Rydberg states of the HD molecule observed by fast neutral-beam photofragment spectroscopy

The four states of the 1s3s, 1s3d triplet gerade complex and the metastable 1s2p c 3Π−u state of HD are studied by laser photofragment spectroscopy in a fast mass- and state-selected neutral beam. The spectra are assigned using a model for the l uncoupling in the 3s, 3d complex. Precise experimental...

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Bibliographic Details
Published in:The Journal of chemical physics 1987-03, Vol.86 (5), p.3050-3051
Main Authors: KEIDING, S, BJERRE, N, HELM, H
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Exact sciences and technology
Molecular properties and interactions with photons
Physics
Properties of molecules and molecular ions
Rotation, vibration and vibration-rotation constants
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Summary:The four states of the 1s3s, 1s3d triplet gerade complex and the metastable 1s2p c 3Π−u state of HD are studied by laser photofragment spectroscopy in a fast mass- and state-selected neutral beam. The spectra are assigned using a model for the l uncoupling in the 3s, 3d complex. Precise experimental molecular constants are obtained for the c state.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.452010