Millimeter and submillimeter wave spectroscopy of protonated and deuterated nitrous oxide

The a- and b-type rotational spectra of the protonated and deuterated nitrous oxide have been investigated in the millimeter and submillimeter frequency range. The molecular ions were produced in a magnetically confined glow discharge. The comparison between the accurate molecular constants deduced...

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Bibliographic Details
Published in:The Journal of chemical physics 1988-02, Vol.88 (4), p.2108-2111
Main Authors: BOGEY, M, DEMUYNCK, C, DESTOMBES, J.-L
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Exact sciences and technology
Molecular properties and interactions with photons
Physics
Properties of molecules and molecular ions
Rotation, vibration and vibration-rotation constants
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Summary:The a- and b-type rotational spectra of the protonated and deuterated nitrous oxide have been investigated in the millimeter and submillimeter frequency range. The molecular ions were produced in a magnetically confined glow discharge. The comparison between the accurate molecular constants deduced from the analysis of the spectra and different sets deduced from ab initio calculations gives structural information on the observed species: the experimental spectra belong to the O-protonated and -deuterated nitrous oxide.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.454092