Charge transfer interaction between a pair of electronically excited moieties: very slow charge neutralization of intramolecular ion pairs formed by biphotonic excitation of diarylmethanes

It is shown that biphotonic excitation of diarylmethanes leads to the formation of ion pairs with extremely long time scale of charge recombination.

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Bibliographic Details
Published in:The Journal of chemical physics 1988-10, Vol.89 (8), p.5345-5347
Main Authors: MODIANO, S. H, LOCKE, R. J, LIM, E. C
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Exact sciences and technology
Molecular properties and interactions with photons
Molecular spectra
Physics
Ultraviolet spectra
Visible spectra
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Description
Summary:It is shown that biphotonic excitation of diarylmethanes leads to the formation of ion pairs with extremely long time scale of charge recombination.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.455628