Photodissociation of iodine complexes in relation to the cage effect

The photodissociation I2M+hν→I2+M was studied for M=C2H6 and M=(C2H5)2O with excitation above the dissociation limit of I2 B state. Vibrational population distributions of the I2(B) product molecules are reported. The results are compared to previous studies of the dissociation of similar iodine com...

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Bibliographic Details
Published in:The Journal of chemical physics 1990-12, Vol.93 (12), p.8676-8681
Main Authors: PHILIPPOZ, J.-M, MONOT, R, VAN DEN BERGH, H
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Exact sciences and technology
Molecular properties and interactions with photons
Photon interactions with molecules
Physics
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Summary:The photodissociation I2M+hν→I2+M was studied for M=C2H6 and M=(C2H5)2O with excitation above the dissociation limit of I2 B state. Vibrational population distributions of the I2(B) product molecules are reported. The results are compared to previous studies of the dissociation of similar iodine complexes and to studies of the cage effect in high density gases and liquids.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.459254