Electronic transition moment variation and Einstein coefficients for the NO(B2Π-X2Π)system

• Published in: The Journal of chemical physics 1991-06, Vol.94 (12), p.7667-7676
• Main Authors: PIPER, L. G, TUCKER, T. R, CUMMINGS, W. P
• Format: Article
• Language: English
• Subjects: Atomic and molecular physics; Exact sciences and technology; Intensities and shapes of molecular spectral lines and bands; Molecular properties and interactions with photons; Physics
• ISSN: 0021-9606; 1089-7690
• DOI: 10.1063/1.460722

This paper details an investigation of the variation in the electronic transition moment with internuclear separation for the NO(B2Π–X2Π) transition. Measurements of the relative intensities of a number of NO B–X vibronic transitions having a common upper level were used to construct a relative transition-moment function between 1.27 and 1.60 Å. After normalizing this relative function by experimentally determined radiative lifetimes, the transition-moment function was extended down to 1.23 Å by incorporating data from oscillator strength measurements. In contrast to empirical transition-moment functions that have been proposed previously, the function in this paper decreases with increasing internuclear separation. Unlike these other functions, however, this one is consistent with theoretical predictions, with most available oscillator strength data, and with the observed trend in B-state radiative lifetimes as a function of vibrational level.