Analytical treatment of magnetic field effects in contact geminate recombination of radical ion pairs in solutions of arbitrary polarity

Geminate recombination of radical ion pairs in the presence of magnetic field is considered on the assumption of a contact reaction and exchange and diffusion character of the reagents motion. Analytical expressions for recombination probabilities for arbitrary magnitude of interparticle Coulomb int...

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Bibliographic Details
Published in:The Journal of chemical physics 1993-08, Vol.99 (4), p.2643-2653
Main Authors: SHOKHIREV, N. V, ZHARIKOV, A. A, KRISSINEL, E. B
Format: Article
Language:English
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Summary:Geminate recombination of radical ion pairs in the presence of magnetic field is considered on the assumption of a contact reaction and exchange and diffusion character of the reagents motion. Analytical expressions for recombination probabilities for arbitrary magnitude of interparticle Coulomb interaction are obtained. For the case of high magnetic fields, the influence of a medium polarity and viscosity, the initial separation in a pair and the scavenging reactions rate on recombination probability and CIDNP is studied.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.465227