Failure of linear mixture rule in vibrational relaxation in CO2–CF2Cl2 and CO2–C4H4S mixtures

The experimental data for the deactivation of CO2(00°1) in CO2–CF2Cl2 and CO2–C4H4S mixtures are presented in the temperature range 323–463 K for different compositions. The relaxation rate per unit pressure (Pτ)−1 showed deviations from the linear mixture rule.

Saved in:
Bibliographic Details
Published in:The Journal of chemical physics 1996-06, Vol.104 (24), p.10061-10062
Main Authors: Sircar, Amit, Sarkar, K. Lalita, Chalapati Rao, Y. V.
Format: Article
Language:English
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The experimental data for the deactivation of CO2(00°1) in CO2–CF2Cl2 and CO2–C4H4S mixtures are presented in the temperature range 323–463 K for different compositions. The relaxation rate per unit pressure (Pτ)−1 showed deviations from the linear mixture rule.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.471760