Nucleation in superheated liquid argon–krypton solutions

• Published in: The Journal of chemical physics 1997-04, Vol.106 (13), p.5648-5657
• Main Authors: Baidakov, V. G., Kaverin, A. M., Boltachev, G. Sh
• Format: Article
• Language: English
• ISSN: 0021-9606; 1089-7690
• DOI: 10.1063/1.473585

We report nucleation-rate measurements in metastable liquid argon–krypton solutions at pressures of 1.0 and 1.6 MPa over a wide temperature and concentration range. These measurements were performed with the use of a superheated liquid lifetime measurement method. The experimental results are compared with the homogeneous nucleation theory data both using a macroscopic (capillary) approach and taking into account the dependence of critical bubble surface tension on interface curvature. The size effect in nucleation is considered in the framework of the Van-der-Waals, Cahn–Hilliard method. The experimental data indicate that the homogeneous nucleation theory quantitatively describes the kinetics of a first order phase transition in binary solutions of simple liquids if the size effect is taken into account and nucleation rates are J≳106 m−3 sec−1. At J≲106 m−3 sec−1 there is initiated nucleation. A diffusion spinodal of a solution is approximated. The attainable superheating temperature data are presented.