An infrared spectrum of the molecular dication (doubly positively charged molecule), D35Cl2

We have observed an infrared spectrum within the X 3Σ− state of DCl2+ using a fast-ion-beam/laser-beam spectrometer. A preliminary analysis shows good agreement with the rotational constants and tunneling lifetimes calculated by Bennett and McNab for the ν=1–2 vibrational band, although the calculat...

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Bibliographic Details
Published in:The Journal of chemical physics 1998-02, Vol.108 (5), p.1761-1764
Main Authors: Abusen, Ramadan, Bennett, Frederick R., McNab, Iain R., Sharp, David N., Shiell, Ralph C., Woodward, Clare A.
Format: Article
Language:English
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Summary:We have observed an infrared spectrum within the X 3Σ− state of DCl2+ using a fast-ion-beam/laser-beam spectrometer. A preliminary analysis shows good agreement with the rotational constants and tunneling lifetimes calculated by Bennett and McNab for the ν=1–2 vibrational band, although the calculated band origin appear to be in error by 21.1 cm−1.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.475552