Rate Constants for Reactions of Inorganic Radicals in Aqueous Solution

• Published in: Journal of physical and chemical reference data 1988-07, Vol.17 (3), p.1027-1284
• Main Authors: Neta, P., Huie, Robert E., Ross, Alberta B.
• Format: Article
• Language: English
• Subjects: Chemistry; Exact sciences and technology; Inorganic chemistry and origins of life; Kinetics and mechanism of reactions
• ISSN: 0047-2689; 1529-7845
• DOI: 10.1063/1.555808

Rate constants have been compiled for reactions of various inorganic radicals produced by radiolysis or photolysis, as well as by other chemical means in aqueous solutions. Data are included for the reactions of ⋅CO2 −, ⋅ CO 3⋅ − , O3, ⋅N3, ⋅NH2, ⋅NO2, NO 3⋅ , ⋅ PO 3 2− , PO 4⋅ 2− , SO 2⋅ − , ⋅ SO 3 − , SO 4⋅ − , ⋅ SO 5⋅ − , ⋅ SeO 3⋅ − , ⋅ (SCN) 2⋅ − , ⋅ CL 2⋅ − , ⋅ Br 2⋅ − , ⋅ I 2⋅ − , ⋅ ClO 2⋅ , ⋅ BrO 2⋅ , and miscellaneous related radicals, with inorganic and organic compounds.