Proton exchange for high-index waveguides in LiNbO3

We describe the fabrication and characterization of optical waveguides formed in LiNbO3 by proton exchange in benzoic acid melts at 200–250 °C. Proton exchange, in LiNbO3 the replacement of lithium ions with protons, takes place when the substrate is immersed in the molten acid. We observe a surface...

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Bibliographic Details
Published in:Applied physics letters 1982-10, Vol.41 (7), p.607-608
Main Authors: Jackel, J. L., Rice, C. E., Veselka, J. J.
Format: Article
Language:English
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Summary:We describe the fabrication and characterization of optical waveguides formed in LiNbO3 by proton exchange in benzoic acid melts at 200–250 °C. Proton exchange, in LiNbO3 the replacement of lithium ions with protons, takes place when the substrate is immersed in the molten acid. We observe a surface increase in the refractive index of 0.12, for the extraordinary polarization only, with a step function index profile. This is the highest index increase obtainable to date for LiNbO3. Measured diffusion rates for x-cut crystals are 1.37 μm2/h at T = 249 °C and 0.37 μm2/h at T = 217 °C, so that very deep guides can be formed in short times. Diffusion is somewhat slower in the z direction. The process as described is not useful for y-cut crystals, since it damgaes this surface. Losses, measured on x-cut samples, were
ISSN:0003-6951
1077-3118
DOI:10.1063/1.93615