Observation of magnetic-field-induced ferroelectricity in a compound CaFe3O(PO4)3

Geometrically frustrated kagome materials reveal many novel states of matter ranging from quantum spin liquids to multiferroics. Herein, we study the compound CaFe3O(PO4)3, which has a quasi-two-dimensional lattice of Fe3+ ions with spin S = 5/2. Electrical and magnetic properties have been investig...

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Published in:Journal of applied physics 2023-04, Vol.133 (16)
Main Authors: Voma, U. K., Shahee, A., Kim, Kwang-Tak, Lee, Jungwoo, Boya, K., Bhowal, S., Kim, Kee Hoon, Koteswararao, B.
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Language:English
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Applied physics
Couplings
Ferroelectric materials
Ferroelectricity
Ferromagnetism
Magnetic properties
Spin liquid
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cited_by cdi_FETCH-LOGICAL-c362t-2827ccedbe2c9dc3c58125723ae1eeeed760d8ba449df547d98a41dc6f6044823
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container_issue 16
container_start_page
container_title Journal of applied physics
container_volume 133
creator Voma, U. K.
Shahee, A.
Kim, Kwang-Tak
Lee, Jungwoo
Boya, K.
Bhowal, S.
Kim, Kee Hoon
Koteswararao, B.
description Geometrically frustrated kagome materials reveal many novel states of matter ranging from quantum spin liquids to multiferroics. Herein, we study the compound CaFe3O(PO4)3, which has a quasi-two-dimensional lattice of Fe3+ ions with spin S = 5/2. Electrical and magnetic properties have been investigated on polycrystalline specimens of CaFe3O(PO4)3 using magnetization, pyroelectric, and magnetoelectric current measurements. The system undergoes a weak ferromagnetic-type ordering at TC1 ∼ 19.5 K, followed by another transition at TC2 ∼ 9 K. While no ferroelectric polarization (P) is observed at a zero magnetic field (H), the applied H induces P below TC2. At the temperature of 2.5 K, P starts to increase above H of 1 T, shows a maximum value at 3.15 T, and then decreases at higher H regions. The observed results suggest that CaFe3O(PO4)3 should be a magnetic-field-induced ferroelectric compound with frustrated magnetic couplings.
doi_str_mv 10.1063/5.0138374
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source American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list)
subjects Applied physics
Couplings
Ferroelectric materials
Ferroelectricity
Ferromagnetism
Magnetic properties
Spin liquid
title Observation of magnetic-field-induced ferroelectricity in a compound CaFe3O(PO4)3
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