The Schmidt Rearrangement of Methyl Furoxanyl Ketones and Furoxancarboxylic Acids: a New Synthetic Route to Aminofuroxans

The Schmidt rearrangement of methyl furoxanyl ketones and furoxancarboxylic acids has been carried out for the first time, exemplified by 3,4-diacetylfuroxan and 4-carboxy-3-(ethoxycarbonyl)furoxan, and this reaction has been shown to be a convenient method for the preparation of aminofuroxans.

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Bibliographic Details
Published in:Mendeleev communications 1995, Vol.5 (2), p.56-58
Main Authors: Makhova, Nina N., Blinnikov, Alexander N., Khmel’nitskii, Lenor I.
Format: Article
Language:English
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Summary:The Schmidt rearrangement of methyl furoxanyl ketones and furoxancarboxylic acids has been carried out for the first time, exemplified by 3,4-diacetylfuroxan and 4-carboxy-3-(ethoxycarbonyl)furoxan, and this reaction has been shown to be a convenient method for the preparation of aminofuroxans.
ISSN:0959-9436
DOI:10.1070/MC1995v005n02ABEH000455