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Enantiomeric NMR analysis of organic acids with the Corey chiral controller

( R,R)-1,2-Di-(2,4,6-trimethylbenzylamino)-1,2-diphenylethane (the Corey chiral controller) was found to be an effective chiral NMR shift reagent for the determination of the enantiomer ratio in chiral carboxylic and sulfonic acids and cyclic β-diketones.

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Bibliographic Details
Published in:Mendeleev communications 1999, Vol.9 (4), p.149-151
Main Authors: Lapitskaya, Margarita A., Zatonsky, Georgy V., Pivnitsky, Kasimir K.
Format: Article
Language:English
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Summary:( R,R)-1,2-Di-(2,4,6-trimethylbenzylamino)-1,2-diphenylethane (the Corey chiral controller) was found to be an effective chiral NMR shift reagent for the determination of the enantiomer ratio in chiral carboxylic and sulfonic acids and cyclic β-diketones.
ISSN:0959-9436
DOI:10.1070/MC1999v009n04ABEH001085