Alkylation and phenylation of [60]- and [70]-fullerenes by the reaction with ketones in the ionization chamber of a mass spectrometer

The title reactions proceed under electron impact ( EI) and are accompanied by hydrogen addition and loss; the reaction of C 60 with acetone has been shown to occur at least partly at the walls of the ionization chamber and experimental evidence suggests a radical path process involving EI generatio...

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Bibliographic Details
Published in:Mendeleev communications 1999, Vol.9 (5), p.176-177
Main Authors: Shilova, Elena A., Lyakhovetsky, Yury I., Tumanskii, Boris L., Belokon, Alexander I., Nekrasov, Yurii S.
Format: Article
Language:English
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Summary:The title reactions proceed under electron impact ( EI) and are accompanied by hydrogen addition and loss; the reaction of C 60 with acetone has been shown to occur at least partly at the walls of the ionization chamber and experimental evidence suggests a radical path process involving EI generation of methyl radicals from acetone
ISSN:0959-9436
DOI:10.1070/MC1999v009n05ABEH001178