α-Ferrocenylvinylacetylenes

Thermolysis of 3-isopropyl- and 3-cyclobutyl-3-ferrocenylcyclopropenes results in the formation of 3-alkylidene-3-ferrocenylpropynes and ( Z,E)-1-alkyl-1-ferrocenylpropenes; 2,2-dibromo-1-methyl-, 2,2-dibromo-1-isopropyl- and 2,2-dibromo-1-cyclobutylferrocenylcyclopropanes are converted into ferroce...

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Published in:Mendeleev communications 1999, Vol.9 (6), p.234-236
Main Authors: Klimova, Elena I., Garcia, Marcos Martinez, Klimova, Tatiana, Ramirez, Lena Ruiz, Mendez Stivalet, Jose Manuel
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Language:English
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description Thermolysis of 3-isopropyl- and 3-cyclobutyl-3-ferrocenylcyclopropenes results in the formation of 3-alkylidene-3-ferrocenylpropynes and ( Z,E)-1-alkyl-1-ferrocenylpropenes; 2,2-dibromo-1-methyl-, 2,2-dibromo-1-isopropyl- and 2,2-dibromo-1-cyclobutylferrocenylcyclopropanes are converted into ferrocenylvinylacetylenes on treatment with Bu tOK in THF.
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title α-Ferrocenylvinylacetylenes
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