Synthesis of closo-monocarbon carborane-substituted natural porphyrins

Previously unknown 1,3,5,8-tetramethyl-6,7-di[2′-( closo-monocarbon carborane-1″-yl caesium)methoxycarbonylethyl]porphyrin and 1,3,5,8-tetramethyl-2,4-divinyl-6,7-di[2′-( closo-monocarbon carborane-1″-yl caesium)methoxycarbonylethyl]porphyrin were synthesised in the reactions of deuteroporphyrin IX...

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Bibliographic Details
Published in:Mendeleev communications 2001, Vol.11 (1), p.14-15
Main Authors: Ol'shevskaya, Valentina A., Evstigneeva, Rima P., Luzgina, Valentina N., Gyul’malieva, Maya A., Petrovskii, Pavel V., Morris, John H., Zakharkin, Leonid I.
Format: Article
Language:English
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Summary:Previously unknown 1,3,5,8-tetramethyl-6,7-di[2′-( closo-monocarbon carborane-1″-yl caesium)methoxycarbonylethyl]porphyrin and 1,3,5,8-tetramethyl-2,4-divinyl-6,7-di[2′-( closo-monocarbon carborane-1″-yl caesium)methoxycarbonylethyl]porphyrin were synthesised in the reactions of deuteroporphyrin IX and protoporphyrin IX, respectively, with (1-hydroxymethyl- closo-monocarbon carborane)caesium.
ISSN:0959-9436
DOI:10.1070/MC2001v011n01ABEH001383