Multinuclear NMR-spectroscopic characterization of alkylperoxo complexes of molybdenum(VI)

An alkylperoxo molybdenum(VI) intermediate was identified in the reaction of Bu tOOH with the 1,2-cyclohexanediolo complex of molybdenum(VI) in CHCl 3 using 13C, 17O and 95Mo NMR spectroscopy.

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Bibliographic Details
Published in:Mendeleev communications 2003, Vol.13 (1), p.8-9
Main Authors: Dorosheva, Tatiana S., Bryliakov, Konstantin P., Talsi, Evgenii P.
Format: Article
Language:English
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Summary:An alkylperoxo molybdenum(VI) intermediate was identified in the reaction of Bu tOOH with the 1,2-cyclohexanediolo complex of molybdenum(VI) in CHCl 3 using 13C, 17O and 95Mo NMR spectroscopy.
ISSN:0959-9436
DOI:10.1070/MC2003v013n01ABEH001636