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Chiral P -monodentate phosphite ligand for Pd-catalysed asymmetric allylation reactions

Monodentate diamidophosphite ligand 2 with stereogenic phosphorus and carbon atoms, which is easily available from ( S)-2-phenylaminomethyl pyrrolidine, is an effective chiral inductor in Pd-catalysed asymmetric allylation reactions.

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Bibliographic Details
Published in:Mendeleev communications 2003, Vol.13 (3), p.134-135
Main Authors: Gavrilov, Konstantin N., Tsarev, Vasily N., Lyubimov, Sergey E., Shyryaev, Alexei A., Zheglov, Sergey V., Bondarev, Oleg G., Davankov, Vadim A., Kabro, Anzhelika A., Moiseev, Sergey K., Kalinin, Valery N.
Format: Article
Language:English
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Description
Summary:Monodentate diamidophosphite ligand 2 with stereogenic phosphorus and carbon atoms, which is easily available from ( S)-2-phenylaminomethyl pyrrolidine, is an effective chiral inductor in Pd-catalysed asymmetric allylation reactions.
ISSN:0959-9436
1364-557X
DOI:10.1070/MC2003v013n03ABEH001745