Erbium and ytterbium complexes with phosphates and phosphine oxides

The new complexes of erbium and ytterbium with amine, phosphate and phosphine oxide ligands Ln(NH 2R) 3Cl 3, Ln[O P(NMe 2) 2NHR] 3Cl 3, Ln[O P(OPh) 2NHR] 3Cl 3, [R CH 2CH 2CH 2Si(OEt) 3], Ln[O P(OPh) 3] 3Cl 3, Ln[O P(CH 2CH 2CF 3) 3] 3Cl 3 and Ln[O P(CH CHPh) 3] 3Cl 3 have been synthesised, and thei...

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Published in:Mendeleev communications 2004, Vol.14 (3), p.109-111
Main Authors: Bushuk, Boris A., Bushuk, Sergei B., Cherepennikova, Nadezhda F., Douglas, William E., Fukin, Georgii K., Grigoriev, Iliya S., Klapshina, Larisa G., van der Lee, Arie, Semenov, Vladimir V.
Format: Article
Language:English
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Summary:The new complexes of erbium and ytterbium with amine, phosphate and phosphine oxide ligands Ln(NH 2R) 3Cl 3, Ln[O P(NMe 2) 2NHR] 3Cl 3, Ln[O P(OPh) 2NHR] 3Cl 3, [R CH 2CH 2CH 2Si(OEt) 3], Ln[O P(OPh) 3] 3Cl 3, Ln[O P(CH 2CH 2CF 3) 3] 3Cl 3 and Ln[O P(CH CHPh) 3] 3Cl 3 have been synthesised, and their absorption spectra have been measured in both films and solutions.
ISSN:0959-9436
DOI:10.1070/MC2004v014n03ABEH001894