Chemically induced magnetic isotope effect on tin nuclei

A magnetic isotope effect on 117Sn and 119Sn nuclei was observed for the first time in the photolysis of (1-naphthylmethyl)-trimethyltin 1. The isotope effect is accompanied by the fractionation of magnetic and non-magnetic tin isotopes: the magnetic isotopes are accumulated in starting compound 1,...

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Bibliographic Details
Published in:Mendeleev communications 2005, Vol.15 (1), p.4-6
Main Authors: Buchachenko, Anatolii L., Roznyatovsky, Vitaly A., Ivanov, Vladimir L., Ustynyuk, Yuri A.
Format: Article
Language:English
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Summary:A magnetic isotope effect on 117Sn and 119Sn nuclei was observed for the first time in the photolysis of (1-naphthylmethyl)-trimethyltin 1. The isotope effect is accompanied by the fractionation of magnetic and non-magnetic tin isotopes: the magnetic isotopes are accumulated in starting compound 1, whereas the non-magnetic isotopes predominate in the photolysis product, hexamethyldistannane 2.
ISSN:0959-9436
DOI:10.1070/MC2005v015n01ABEH001998