Synthesis, properties and reactivity of intramolecular hypercoordinate silicon complexes

The state of the art of the chemistry of hypercoordinate silicon compounds is analyzed. Published data on the current top-priority approaches to the preparative synthesis of these compounds and on their properties, structures and reactivity are summarized and generalized. Relying on the results obta...

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Bibliographic Details
Published in:Russian chemical reviews 2014-01, Vol.83 (9), p.848-883
Main Authors: Nikolin, A A, Negrebetsky, V V
Format: Article
Language:English
Subjects:
Silicon
Silicon compounds
State of the art
Synthesis
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Summary:The state of the art of the chemistry of hypercoordinate silicon compounds is analyzed. Published data on the current top-priority approaches to the preparative synthesis of these compounds and on their properties, structures and reactivity are summarized and generalized. Relying on the results obtained by modern physicochemical methods, the possible mechanisms of stereodynamic processes occurring in the coordination units of hypercoordinate silicon complexes are discussed. The bibliography includes 157 references.
ISSN:0036-021X
1468-4837
DOI:10.1070/RC2014v083n09ABEH004385