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Barocaloric effect in ferroelastic fluorides and oxyfluorides
Using the data about the temperature - pressure phase diagram and the phase transition entropy at ambient and high pressure, intensive and extensive barocaloric effects were analyzed in the region of single and successive order-disorder phase transitions in fluorides and oxyfluorides with the elpaso...
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| Published in: | Ferroelectrics 2016-08, Vol.500 (1), p.153-163 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c418t-bb7971a953c3f1b2d473b98f7a4e00eaadff9cf4fb79ed43bc1b235aab57aec33 |
| container_end_page | 163 |
| container_issue | 1 |
| container_start_page | 153 |
| container_title | Ferroelectrics |
| container_volume | 500 |
| creator | Flerov, I. N. Gorev, M. V. Bogdanov, E. V. Laptash, N. M. |
| description | Using the data about the temperature - pressure phase diagram and the phase transition entropy at ambient and high pressure, intensive and extensive barocaloric effects were analyzed in the region of single and successive order-disorder phase transitions in fluorides and oxyfluorides with the elpasolites-cryolite structure. It was found that hydrostatic as well as chemical pressure are the effective tools to change the entropy of compounds with disordered ionic groups or atoms in structure and to realize the significant intensive and extensive barocaloric effects comparable with the values of baro- and magnetocaloric effects, characteristic for materials, considered as promising solid refrigerants. |
| doi_str_mv | 10.1080/00150193.2016.1214525 |
| format | article |
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It was found that hydrostatic as well as chemical pressure are the effective tools to change the entropy of compounds with disordered ionic groups or atoms in structure and to realize the significant intensive and extensive barocaloric effects comparable with the values of baro- and magnetocaloric effects, characteristic for materials, considered as promising solid refrigerants.</description><subject>Atomic structure</subject><subject>barocaloric effect</subject><subject>Entropy</subject><subject>Ferroelectric materials</subject><subject>Fluorides</subject><subject>Hydrostatics</subject><subject>Oxyfluorides</subject><subject>Phase diagrams</subject><subject>Phase transformations</subject><subject>Phase transition</subject><subject>Phase transitions</subject><subject>thermal properties</subject><issn>0015-0193</issn><issn>1563-5112</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQQIMoWKs_QVjw4mVrZpN0NwdBLX5BwYuew2w2gS3ppia7aP99s7R68OBpmJk3w8wj5BLoDGhFbygFQUGyWUFhPoMCuCjEEZmAmLNcABTHZDIy-QidkrMYVyllnMsJuX3A4DU6H1qdGWuN7rO2y6wJwRuHsU9l64bUbkzMsGsy_739LZyTE4sumotDnJKPp8f3xUu-fHt-Xdwvc82h6vO6LmUJKAXTzEJdNLxktaxsidxQahAba6W23CbONJzVOkFMINaiRKMZm5Lr_d5N8J-Dib1at1Eb57AzfogKKskk8PR-Qq_-oCs_hC5dl6hCCipoCYkSe0oHH2MwVm1Cu8awVUDVKFX9SFWjVHWQmubu9nNtZ31Y45cPrlE9bpNAG7DTbVTs_xU79QJ-LQ</recordid><startdate>20160808</startdate><enddate>20160808</enddate><creator>Flerov, I. 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| ispartof | Ferroelectrics, 2016-08, Vol.500 (1), p.153-163 |
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| language | eng |
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| source | Taylor and Francis:Jisc Collections:Taylor and Francis Read and Publish Agreement 2024-2025:Science and Technology Collection (Reading list) |
| subjects | Atomic structure barocaloric effect Entropy Ferroelectric materials Fluorides Hydrostatics Oxyfluorides Phase diagrams Phase transformations Phase transition Phase transitions thermal properties |
| title | Barocaloric effect in ferroelastic fluorides and oxyfluorides |
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