Ferroelastic lattice instability during the thermally enhanced reaction of MSE

A p-dimethylaminobenzenesulfonate (MSE) polycrystalline powder is converted to the zwitterionic product p-trimethylammoniumbenzenesulfonate (ZWT) by a chemical thermally induced reaction at T= 55,5°C. Experimental results obtained by differential scanning calorimetry and 13C solid-state NMR indicate...

Full description

Saved in:
Bibliographic Details
Published in:Ferroelectrics 1999-09, Vol.233 (1), p.129-137
Main Authors: Even, J., Bertault, M., Gallier, J., Rouede, D.
Format: Article
Language:English
Subjects:
Ferroelastic
MSE
structural phase transition
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A p-dimethylaminobenzenesulfonate (MSE) polycrystalline powder is converted to the zwitterionic product p-trimethylammoniumbenzenesulfonate (ZWT) by a chemical thermally induced reaction at T= 55,5°C. Experimental results obtained by differential scanning calorimetry and 13C solid-state NMR indicate that reaction-induced stress gives rise to a ferroelastic lattice instability during the thermally enhanced solid state reaction of methyl p-dimethylaminobenzenesulfonate (MSE).
ISSN:0015-0193
1563-5112
DOI:10.1080/00150199908017003